We must supply food and clothing to the poor.

Literal

Poor people [to-に] food [and-と] clothing [object-を] must-supply.

供給しなければならない uses the obligation form of する. 供給する is a formal suru-verb meaning 'to supply.' 食料と衣類 joins two nouns exhaustively with と. The subject is omitted — it's a general moral statement about societal obligation.