She enthusiastically struck up a conversation.

Literal

She [topic-は] [eagerly-熱心に] conversation [object-を] started.

Plain transitive sentence with the adverb 熱心に modifying 始めた ('started'). 会話 ('conversation') is paired with 始める ('start') as a standard collocation — also pairs with 弾む ('liven up'), 続ける ('continue'), 終える ('end').