。
She ordered the book from England.
Literal
She [topic-は] that book [object-を] England [to-に] ordered.
A subtle に-trap: in Japanese you 'order to' a place — に marks the destination of the order, where the request is sent — even though English flips this into 'order from.' 注文する takes に for the recipient just like other directional verbs (送る, 出す, 出版する). イギリス is borrowed from Portuguese 'Inglês,' a holdover from 16th-century Portuguese trade — older than most English-derived loanwords. In formal Japanese, the United Kingdom is 連合王国 or 英国; イギリス is the everyday term.