Google Toolbar — blocks pop-up ads

Literal

Popup-ad [obj-を] block 'Google Toolbar'

A headline-style noun phrase: the entire verb phrase ポップアップ広告をブロックする functions as a relative clause modifying 「Google ツールバー」, with no finite verb or copula. The whole utterance is a caption/label, not a sentence. Note the full-width Latin letters (Google) and full-width space, a Japanese typographic convention used so that embedded English reads at Japanese character width.