それ自体 '(the thing) itself / X itself' is the stock reflexive phrase for isolating the subject from its context. おめでたい 'auspicious / congratulation-worthy / happy' is the formal/elevated form of めでたい, with the honorific prefix お. 気になる here appears in its attributive form as a relative clause modifying コメント 'comment' — 'a comment that catches one's attention.' Neatly shows how 気になる can modify nouns directly.