Sorry. I have a part-time job starting in the morning tomorrow.

Literal

Sorry. Tomorrow [topic-は] morning [from-から] part-time-job [subj-が] exist [feminine-のよ].

パート is a clipped loanword from 'part-timer,' used as a noun for a part-time job — especially by women working daytime shifts. The sentence-final のよ combines the explanatory の with the assertive よ, a distinctly feminine speech pattern. ごめんね adds the softening ね to the apology, making it gentle and familiar.