You can catch a glimpse of Mt. Fuji from the train window.

Literal

Train [of-の] window [from-から] Mt. Fuji [subject-が] for-a-moment is-visible.

ちらっと is a mimetic adverb for 'briefly, fleetingly, out of the corner of the eye' — used specifically for things glimpsed momentarily. 見える is the spontaneous-perception verb 'can be seen,' taking が on what's seen. Together ちらっと見える = 'can catch a glimpse of,' a natural way to describe a passing view.