くれぐれも (thoroughly/I urge you) is a strong adverb for earnest warnings. 悪質訪問販売業者 is a dense compound: 悪質 (malicious) + 訪問販売 (door-to-door sales) + 業者 (business operator). 無料点検商法 (free inspection scam) is another compound describing a deceptive sales tactic. ご注意ください is the polite honorific request.