Nothing is more precious than friends.

Literal

Friends-than important-[attributive-な] things [subject-が] not-exist.

The Xより [attribute]ものはない ('nothing is more X than Y') is the superlative construction — 'there is no more X than Y.' 大切 ('important, precious, dear') paired with もの gives 'precious things.' A classic heartfelt statement about the value of friendship.