I'm planning to skip morning work tomorrow.

Literal

Tomorrow, morning [possessive-の] work [topic-は] rest intend [polite-です].

休む has two senses relevant here: 'to rest' and 'to be absent from / skip' (for work, school, etc.). 朝の仕事 = 'morning['s] work' — the の chains 朝 ('morning') as a modifier. Work-life balance declaration.