Let me meet you at the station tomorrow.

Literal

Tomorrow, station [at-で] honorable-welcome let's.

お出迎え = 'welcoming reception, meeting [an arriving person].' The お prefix + the noun form of 出迎える ('to go meet/welcome'). お出迎えしましょう is the humble お~する in ましょう form — a polished 'let me welcome you.' Typical of tour guides or hospitality professionals.